A few thoughts and comments.
OK, your loaded rounds do not all chamber, why?
1) Sizing die not set up correctly. The fix is to screw the die into the press a little at a time until ALL of your sized cases ( no bullet or powder) chamber and extract with ease. Not just some of them, all of them.
2) OAL to long, bullet making contact with the rifling. The fix is to seat the bullet deeper until they chamber.
3) Case mouth flare applied by the Lee Expander die making contact with the chamber walls. The fix is to remove the flare with a taper crimp or a Lee Factory Crimp Die. Better still, forget the Expander die and eliminate this one all together. The fix is to properly "Chamfer" in inside of the case mouth
As for not deburring the cases, I deburred all of them.
Deburring will NOT help a flat based bullet better enter the neck. Deburring is done on the outside of the neck after trimming and has nothing to do with your problem. Your problem is on the inside of the neck. You need to "Chamfer" the inside of the neck so it will accept all bullets both flat and boat-tail. Expander dies are not needed for bottle necked rifle rounds.
You do have the expander button/ball installed on your Full Length die, Yes? Failure to install the button will result in undersized necks that may not accept a flat based bullet.
4) Seating die not set up correctly and buckling the case. The fix is to set up die die so there is no contact with the built in taper crimp.
1) Take a properly sized and trimmed case and place it in the shell holder.
2) Back the seating die way way out of the press.
3) Raise the ram.
4) Screw the seating die into the press until you feel it make contact with the case mouth.
5) Lower the ram
6) Back the seating die OUT of the press at least one FULL turn.
7) Lock it down with the Mickey Mouse rubber "O" ring locking nut.
8) Adjust OAL with seating stem.
9) If a crimp is desired, purchase a Lee Factory Crimp die and leave the seating die set up to seat only.
If it were I that contacted Lee and was told to purchase an "Expander" die I would have been a little pissed. I would have asked the fool if an Expander die is needed to complete the loading process with Lee dies, then why do you no include them in the Lee die sets. I would have accused him of trying to sell me something that is not needed to fix the problem, which is exactly what he did.