Here is the simplest check for the chamber having a diameter too small somewhere (but not a barrel shape or other out of shape defects): Clean the chamber throughly, then take a bunch of your ammo and the upper and just drop them into the chamber. They should go home with a click and fall right out when the muzzle is elevated. If you find any that need to be pushed into the chamber, or that don't drop right out, either something is still dirty or something is too small. Set aside all rounds that give trouble. If all of them are sticky, well, the problem is bad. Clean the chamber again, and recheck those rounds that stuck. If they still do not click in and slide right out, you probably need to send it to the maker and demand that they deliver what you already paid money for. The gentle application of a Wylde reamer is likely to fix this defect...
If the chamber is out of shape, it should be apparent looking at and measuring the fired empties. Look for diameter varying as you go aorund the case, and for anything but a smooth taper as you go from a quarter inch of so from the back end of the case towards the shoulder. If it looks crooked, it probably is. Get the maker to replace the barrel. Oh, and don't count the first 1/4" - it is well supported and does not expand out to the chamber wall.
Good Luck, Billski