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Between nickel boron & hard chrome - I would choose hard chrome.
Nickle boron is "slick" but it is a coating that will show wear & stains if not cleaned frequently.
Hard chrome won't stain. The chrome is hard and will give a long life of service.
Phosphate also is fine - oil it frequently (as an AR should be)
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I have many regular 'mil-spec' Phosphate carriers from Colt, AO Enterprises, and DPMS. More than one for sure from each different brand...
They all work fine and I honestly can't tell any of them apart from each other than noticing / looking for a special mfg mark that might (or might not) be here or there from one mfg to the other. Specifically talking about stuff one would normally be able to see right away like the staking on the gas key and the overall finish of the machining on the carrier on the different contact surfaces.
When I say contact surfaces - Am meaning the rails that slide inside the upper, the bottom at the back that contacts (and cocks) the hammer, the finish inside the gas key and the bore for the bolt, etc.
Considering that my sample size of each is what it is - I can't tell a noticeably visible difference between any of them. Noticeably visible differences that would not need a bore
scope to spot but would otherwise be seen...
Comparing the finish (where parts move and stuff slides) of any of that sort of 'mil-spec' stuff to a Toolcraft NiB carrier assembly is noticeable to me.
I can actually see that Toolcraft polished a lot of stuff before they applied the particular coating.
I am NOT suggesting that any of that extra 'polishing' before coating was 'needed', or going to get off into of the 'if' it may have been an 'improvement' or not garbage but...
I DO like it.
The Colt part in this picture clearly has the finish that it does to be better able to 'hold lube'. That has got to be the superior part...
even though both are within 'spec'.